The incident occurred on NH-55 near Bhawanipali when a group of devotees were returning from Kalpeshwar Temple in Hatibari in a Tata Magic passenger vehicle, said police.
The injured have been admitted at Burla's V.S.S.Medical College and Hospital in Sambalpur.
While four persons had died on the spot, others succumbed to injuries during treatment at hospital, said police.
Chief Minister Naveen Patnaik announced an ex-gratia of Rs 2 lakh each for the kin of the deceased and free treatment to the injured persons.
(This story has not been edited by Social News XYZ staff and is auto-generated from a syndicated feed.)
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